Insight into the effect of additives widely used in lithium–sulfur batteries

Journal: Chemical Communications

Published: 2019-11-19

DOI: 10.1039/c9cc06504k

Affiliations: 2

Authors: 5

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Research Highlight

Lithium–sulfur battery performance adds up

© Monty Rakusen/Getty

© Monty Rakusen/Getty

A study that tests some of the assumptions made about an additive used in experimental next-generation batteries could be a step towards commercializing the rechargeable technology.

Lithium–sulfur batteries could have higher capacities than today’s lithium-ion batteries while being cheaper. However, so far, lithium–sulfur batteries degrade too rapidly for commercial uptake. Their lifespan can be extended by adding lithium nitrate (LiNO3) to the electrolyte, but it is not clear how the additive works.

Researchers from Vidyasirimedhi Institute of Science and Technology have used theoretical reactive molecular dynamics simulations to study the interactions between lithium nitrate and the battery’s lithium anode. They found that additive forms a smooth, dense, protective film over the anode. The film contains LixNOy clusters, which capture the damaging lithium polysulfide compounds that form in the battery and attack the anode and cathode if left unchecked.

This finding could pave the way to improve lithium–sulfur battery lifetime.


Supported content

  1. Chemical Communications 55, 13951–13954 (2019). doi: 10.1039/c9cc06504k
Institutions Share
Department of Chemical and Biomolecular Engineering, VISTEC, Thailand 0.50
Centre of Excellence for Energy Storage Technology (CEST), VISTEC, Thailand 0.50

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