Acid pKa Dependence in O–O Bond Heterolysis of a Nonheme FeIII–OOH Intermediate To Form a Potent FeV═O Oxidant with Heme Compound I-Like Reactivity

Journal: Journal of the American Chemical Society

Published: 2019-10-09

DOI: 10.1021/jacs.9b08442

Affiliations: 1

Authors: 4

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Center for Metals In Biocatalysis (CMB), UMN, United States of America (USA) 1